By Daniel J. Brunelle, Michael Korn
Advances in Polycarbonates contains such issues as conception and modelling, synthesis of recent polycarbonates, characterization, improvement of stronger homes in polycarbonates (such as conductivity, weatherability, greater warmth or greater low temperature ductility), recycling, and approach chemistry. quite a few overseas researchers from undefined, govt, and academia have supplied a various array of contemporary study. BPA-Polycarbonate is a flexible engineering fabric with a mixture of many very important homes: optical-quality transparency and birefringence, excessive refractive index, excessive glass transition temperature, unparalleled influence power and solid processability. Fifty years after its discovery, educational and commercial polycarbonate learn maintains to develop each year. Polycarbonates are utilized in a really huge number of purposes, starting from optical recording media (CD, DVD, etc.), carrying apparatus, unbreakable glazing fabrics, lighting fixtures, clinical apparatus, and automobile exteriors and interiors.
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Additional resources for Advances in Polycarbonates
Korn et al. brominated methylcinnamate terminated P C oligomers (19). Examples for End-functionalized PC Oligomers Table 1 contains some literature examples for end-functionalized P C oligomers prepared via the solution process (Al, A2). The structure of the respective substituted phenol for endgroup modification, the synthetic method chosen, the type of oligomer obtained, the MW(s) of the resulting oligomer(s) (given as a M W range) and the analytical methods reported for their characterization are included.
01 mol) of l,l,l-tris(4'-hydroxyphenyl)ethane, cat. 04 mol) of allyl chloroformate in 3 mL of dry T H F . The reaction was allowed to warm to room temperature and was worked up after 30 h. Oligomers 24. P. 04 mmol) of 27 were dissolved in 10 mL of dry T H F over 30 min. 5 mL of dry T H F was added and the reaction run for 60 min. Afterwards the solution was precipitated from M e O H , the solids filtered, washed and dried. 2 st 3 nd 2 3 n Acknowledgement Compounds and oligomers 1, 18-27 (Table 2e-i) were synthesized during a post-doctoral appointment at U N C , Chapel Hill, N C with Prof.
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Advances in Polycarbonates by Daniel J. Brunelle, Michael Korn